904716

(CAAC-Cy)Rh(COD)Cl

• Synonym(s): [2-[2,6-bis(1-methylethyl)phenyl]-3,3-dimethyl-2-azaspiro[4.5]dec-1-ylidene]chloro[(1,2,5,6-η)-1,5-cyclooctadiene]Rhodium
• Empirical Formula (Hill Notation): C₃₁H₄₇ClNRh
• CAS Number: 1801869-83-9
• Molecular Weight: 572.07
• UNSPSC Code: 12352101
• NACRES: NA.22

Properties

• form: powder or crystals
• storage temp.: −20°C

Description

Application

(CAAC-Cy)Rh(COD)Cl is a selective hydrogenation catalyst used for the hydrogenation of a variety of arenes including fluoroarenes giving access to all-cis-multifluorinated cycloalkanes.1

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Other Notes

Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes

Hydrogenation of fluoroarenes: Direct access to all-cis-(multi)fluorinated cycloalkanes

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable