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Merck

34854

Sigma-Aldrich

Chloroform

suitable for HPLC, ≥99.8%, amylene stabilized

Synonym(e):

Methylidyntrichlorid, Trichlormethan

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About This Item

Empirische Formel (Hill-System):
CHCl3
CAS-Nummer:
Molekulargewicht:
119.38
Beilstein:
1731042
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
41116105
PubChem Substanz-ID:
NACRES:
NA.04
bp:
60.5-61.5 °C (lit.)

Qualität

HPLC grade
amylene stabilized

Qualitätsniveau

Dampfdichte

4.1 (vs air)

Dampfdruck

160 mmHg ( 20 °C)

Assay

≥99.8%

Form

liquid

Methode(n)

HPLC: suitable

Verunreinigungen

Free acid, in accordance
acetone, aldehyde, in accordance (nessler test)
free chlorine (Cl), in accordance
≤0.0005% non-volatile matter
≤0.001% free acid (as HCl)
<0.01% water (Karl Fischer)

Abdampfrückstand

≤0.0005%

Farbe

APHA: ≤10

Durchlässigkeit

250 nm, ≥50%
260 nm, ≥85%
280 nm, ≥99%

Brechungsindex

n20/D 1.445 (lit.)

bp

60.5-61.5 °C (lit.)

mp (Schmelzpunkt)

−63 °C (lit.)

Dichte

1.48 g/mL at 25 °C
1.492 g/mL at 25 °C (lit.)

Anionenspuren

chloride (Cl-): in accordance

Kationenspuren

Pb: ≤0.05 mg/kg

Absorption

in accordance

λ

H2O reference

UV-Absorption

λ: 250 nm Amax: ≤1.00
λ: 260 nm Amax: ≤0.30
λ: 280 nm Amax: ≤0.005

Eignung

passes test for reaction against H2SO4
passes test for suitability of determ. w. dithizone

Anwendung(en)

food and beverages

SMILES String

ClC(Cl)Cl

InChI

1S/CHCl3/c2-1(3)4/h1H

InChIKey

HEDRZPFGACZZDS-UHFFFAOYSA-N

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Allgemeine Beschreibung

Chloroform, a halogenated hydrocarbon, is widely employed as a solvent. Its photochemical degradation has been investigated in the presence of TiO2 aqueous suspensions (wavelength range of 310-380nm).

Anwendung

Chloroform has been employed for the ion exchange isolation of sulfatides from the urinary samples by using DEAE-cellulose membranes before the tandem mass spectrometric analysis. It has been used as a solvent for the Langmuir-Blodgett (LB) deposition of lipid bilayers over mica sheets (silver coated back).†

Sonstige Hinweise

Important notice
  • The article number 34854-4X2.5L will be discontinued. Please order the single bottle 34854-2.5L which is physically identical with the same exact specifications.

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Piktogramme

Skull and crossbonesHealth hazard

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 - STOT SE 3

Zielorgane

Central nervous system, Liver,Kidney

Lagerklassenschlüssel

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

does not flash

Flammpunkt (°C)

does not flash


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