C39601

Chlordiphenylphosphin

96%

• Synonym(e): P-Chlordiphenylphosphin, Diphenylphosphinigsäurechlorid
• Lineare Formel: (C₆H₅)₂PCl
• CAS-Nummer: 1079-66-9
• Molekulargewicht: 220.63
• Beilstein: 512032
• EG-Nummer: 214-093-2
• MDL-Nummer: MFCD00000529
• UNSPSC-Code: 12352128
• PubChem Substanz-ID: 24892660
• NACRES: NA.22

Eigenschaften

• Dampfdichte: 7.8 (vs air)
• Qualitätsniveau: 100
• Assay: 96%
• Form: liquid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling
• Brechungsindex: n20/D 1.636 (lit.)
• bp: 320 °C (lit.)
• Dichte: 1.194 g/mL at 25 °C; 1.229 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: phosphine
• SMILES String: ClP(c1ccccc1)c2ccccc2
• InChI: 1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
• InChIKey: XGRJZXREYAXTGV-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Ph₂PCl is an efficient reagent for cross-coupling reactions and for introducing the Ph₂P group into molecules.

Anwendung

Used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation.

Precursors used in the synthesis of various phosphines.

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H290,H302,H314,H412
• P-Sätze: P234 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 1
• Flammpunkt (°F): 280.4 °F
• Flammpunkt (°C): 138 °C
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter