923443

PhMPhos

• Synonym(e): 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
• Empirische Formel (Hill-System): C₄₂H₄₈FeP₂
• Molekulargewicht: 670.62
• UNSPSC-Code: 12352200
• NACRES: NA.21

Eigenschaften

• Form: powder
• Qualitätsniveau: 100
• Eignung der Reaktion: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• Funktionelle Gruppe: phosphine

Beschreibung

Anwendung

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Sonstige Hinweise

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable