905305

(S,S,S)-SPIRAP

≥95%

• Synonym(e): ((1S,3S,3′S)-3,3′-diethyl-3H,3′H-1,1′-spirobi[isobenzofuran]-7,7′-diyl)bis(diphenylphosphane), (S)-CrabPhos
• Empirische Formel (Hill-System): C₄₃H₃₈O₂P₂
• Molekulargewicht: 648.71
• UNSPSC-Code: 12161600

Eigenschaften

• Assay: ≥95%
• Form: powder or crystals
• Eignung der Reaktion: reaction type: Asymmetric synthesis; reagent type: ligand
• mp (Schmelzpunkt): 226-228 °C
• Funktionelle Gruppe: phosphine
• SMILES String: CC[C@H](O1)C2=C([C@@]1(O[C@@H]3CC)C4=C3C=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6)C(P(C7=CC=CC=C7)C8=CC=CC=C8)=CC=C2

Beschreibung

Anwendung

(S,S,S)-SPIRAP is a chiral C₂-symmetric spiroketal-containing ligand developed in the Nagorny lab for asymmetric catalysis. It can be used in variety of stereoselective transformations, including: Ir-catalyzed hydroarylation, Pd-catalyzed allylic alkylation, Pd-catalyzed Heck couplings, and Rh-catalyzed hydrogenation.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Sonstige Hinweise

Design, Synthesis, and Application of Chiral C₂-Symmetric Spiroketal-Containing Ligands in Transition-Metal Catalysis

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable