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Merck

759546

Sigma-Aldrich

Lithium iron(II) phosphate

greener alternative

powder, <5 μm particle size (BET), >97% (XRF)

Synonym(e):

Ferrous lithium phosphate, Iron lithium phosphate, LFP, Triphylite

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About This Item

Lineare Formel:
LiFePO4
CAS-Nummer:
Molekulargewicht:
157.76
UNSPSC-Code:
26111700
NACRES:
NA.23

Qualität

battery grade

Qualitätsniveau

Assay

>97% (XRF)

Form

powder

Mol-Gew.

Mw 157.76 g/mol

Zusammensetzung

LiFePO4

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Partikelgröße

<5 μm (BET)

mp (Schmelzpunkt)

>300 °C (lit.)

Dichte

3.6 g/cm3 (lit.)

Anwendung(en)

battery manufacturing

Grünere Alternativprodukt-Kategorie

InChI

1S/Fe.Li.H3O4P/c;;1-5(2,3)4/h;;(H3,1,2,3,4)/q+2;+1;/p-3

InChIKey

GELKBWJHTRAYNV-UHFFFAOYSA-K

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Allgemeine Beschreibung

Lithium iron(II) phosphate (LiFePO4), also called LFP, is a crystalline, grey-to-black powder with an olivine crystal structure. This unique structure facilitates efficient diffusion of lithium-ions, thanks to the three-dimensional interconnected iron phosphate tetrahedra that form pathways for lithium ions to diffuse. Additionally, the structure is highly stable, not deforming, even after thousands of cycles of lithium intercalation. Our LiFePO4 powder is manufactured to meet high purity with a tightly controlled particle size of less than 5 μm.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more details.

Anwendung

LiFePO4 is a widely used cathode for rechargeable Li batteries. It has high energy density, wide operating temperature, thermal stability, long cycle life and application life, environmental friendliness, and safety that make it a promising electrode material for greener and safer lithium-ion batteries.

Leistungsmerkmale und Vorteile

LiFePO4-based batteries can last longer, operate safely and reliably, and power devices in a wide range of temperatures.
✔ Achieves 1000s of cycles
✔ Safer than cobalt or manganese-based cathode materials
✔ Reliable performance

Rechtliche Hinweise

Product of Engi-Mat Co.

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


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P Subramanya Herle et al.
Nature materials, 3(3), 147-152 (2004-03-03)
The provision of efficient electron and ion transport is a critical issue in an exciting new group of materials based on lithium metal phosphates that are important as cathodes for lithium-ion batteries. Much interest centres on olivine-type LiFePO(4), the most
Kim, G. T.; et al.
Journal of Power Sources, 196, 2187-2187 (2011)
Low temperature hydrothermal synthesis of battery grade lithium iron phosphate
Benedek P, et al.
Royal Society of Chemistry Advances, 7(29), 17763-17767 (2017)
Byoungwoo Kang et al.
Nature, 458(7235), 190-193 (2009-03-13)
The storage of electrical energy at high charge and discharge rate is an important technology in today's society, and can enable hybrid and plug-in hybrid electric vehicles and provide back-up for wind and solar energy. It is typically believed that

Artikel

Professor Qiao’s laboratory lays out recent advances in conversion type lithium metal fluoride batteries. This review explores key concepts in developing electrochemically stable microstructures for wide Li-ion insertion channels.

Professor Qiao’s laboratory lays out recent advances in conversion type lithium metal fluoride batteries. This review explores key concepts in developing electrochemically stable microstructures for wide Li-ion insertion channels.

Electrode Materials for Lithium Ion Batteries

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

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