731382

(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-Bipyrrolidinbis(acetonitril)eisen(II)-Hexafluorantimonat

• Synonym(e): Eisen(II)-(R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)-pyrrolidin-2-yl]-pyrrolidin-1-yl}-methyl-)pyridin)(bis-acetonitril)-hexafluoroantimonat, Fe(R,R-PDP), White-Chen-Katalysator, [Fe(R,R-PDP)(CH₃CN)₂](SbF₆)₂
• Empirische Formel (Hill-System): C₂₄H₃₂F₁₂FeN₆Sb₂
• CAS-Nummer: 1361315-26-5
• Molekulargewicht: 931.90
• MDL-Nummer: MFCD16038114
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329764650
• NACRES: NA.22

Eigenschaften

• Form: powder
• Eignung der Reaktion: core: iron; reagent type: catalyst
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp (Schmelzpunkt): 215-226 °C
• Grünere Alternativprodukt-Kategorie: , Aligned
• SMILES String: [Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4
• InChI: 1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1
• InChIKey: XUNWHBGEOCZDBX-QSKJABRXSA-B

Beschreibung

Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Anwendung

Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable