704954

Chloro-(2-dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2-aminoethyl)-phenyl)]-palladium(II)

• Synonym(e): (2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2-aminoethyl)-phenyl)]-palladium(II)-chlorid, (XPhos)-palladium(II)-phenethylaminchlorid
• Empirische Formel (Hill-System): C₄₁H₅₉ClNPPd
• CAS-Nummer: 1028206-56-5
• Molekulargewicht: 738.76
• MDL-Nummer: MFCD13194128
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 329762494
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Leistungsmerkmale: generation 1
• Eignung der Reaktion: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• mp (Schmelzpunkt): 205-210 °C
• Funktionelle Gruppe: phosphine
• SMILES String: NCCc1ccccc1[Pd]Cl.CC(C)c2cc(C(C)C)c(c(c2)C(C)C)-c3ccccc3P(C4CCCCC4)C5CCCCC5
• InChI: 1S/C33H49P.C8H10N.ClH.Pd/c1-23(2)26-21-30(24(3)4)33(31(22-26)25(5)6)29-19-13-14-20-32(29)34(27-15-9-7-10-16-27)28-17-11-8-12-18-28;9-7-6-8-4-2-1-3-5-8;;/h13-14,19-25,27-28H,7-12,15-18H2,1-6H3;1-4H,6-7,9H2;1H;/q;;;+1/p-1
• InChIKey: HTAJCNQBAFZEJO-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

Material may contain up to 5% pentane

Anwendung

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyst used for:

• Amination / cyclization reactions
• C-N bond-forming reactions via packed-bed microreactors
• Boration of aryl chlorides
• Arylation of oxazole
• Cross-coupling reactions

Rechtliche Hinweise

Usage subject to US Patents 6307087 and 6395916.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335,H412
• P-Sätze: P261 - P264 - P271 - P273 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Aquatic Chronic 3 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves