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Merck

700428

Sigma-Aldrich

N,N-Dimethylformamid-d7

≥99.5 atom % D, contains 0.03 % (v/v) TMS

Synonym(e):

DMF-d7, Heptadeutero-N,N-dimethylformamid

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About This Item

Lineare Formel:
DCON(CD3)2
CAS-Nummer:
Molekulargewicht:
80.14
Beilstein:
1908468
MDL-Nummer:
UNSPSC-Code:
12142201
PubChem Substanz-ID:
NACRES:
NA.21

Isotopenreinheit

≥99.5 atom % D

Qualitätsniveau

Assay

≥99% (CP)

Form

solution

Enthält

0.03 % (v/v) TMS

Methode(n)

NMR: suitable

Verunreinigungen

≤0.05% water
water

Brechungsindex

n20/D 1.428 (lit.)

bp

153 °C (lit.)

Dichte

1.03 g/mL at 25 °C (lit.)

Massenverschiebung

M+7

SMILES String

[2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D

InChIKey

ZMXDDKWLCZADIW-YYWVXINBSA-N

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Allgemeine Beschreibung

N,N-Dimethylformamide-d7 (DMF-d7) is a deuterated NMR solvent containing 0.03% (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. Pulsed neutron diffraction measurements of different concentrations of molar lithium chloride (LiCl) solutions in DMF-d7 have been carried out to investigate the chloride ion solvation.

Anwendung

N,N-Dimethylformamide-d7 may be used to analyze the degree of acrylation by proton NMR during the preparation of polyethylene glycol diacrylate (PEG-DA) from poly(ethylene glycol) (PEG).

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Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

136.4 °F - closed cup

Flammpunkt (°C)

58 °C - closed cup


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Samuel Furse et al.
FEBS letters, 589(19 Pt B), 2726-2730 (2015-08-15)
This paper describes a study of the phospholipid profile of Escherichia coli MG1655 cultures at the B and D periods of the cell cycle. The results indicate that the phosphatidyl glycerol fraction grows relatively rapidly and that the size of
Neutron diffraction study on chloride ion solvation in water, methanol, and N,N-dimethylformamide.
Yamagami M, et al.
J. Chem. Phys., 103(18), 8174-8178 (1995)
Małgorzata Fabijańska et al.
Dalton transactions (Cambridge, England : 2003), 44(3), 938-947 (2014-08-12)
This paper describes the synthesis of trans-bis-(3-aminoflavone)dichloridoplatinum(ii) (trans-Pt(3-af)2Cl2; TCAP) for use as a potential anticancer compound, and the evaluation of its structure by elemental and spectral analyses, and X-ray crystallography. The complex demonstrated a significant cytotoxic effect against human and
Seung Bin Baek et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(46), 14156-14161 (2015-11-19)
Crystallographic observation of adsorbed gas molecules is a highly difficult task due to their rapid motion. Here, we report the in situ single-crystal and synchrotron powder X-ray observations of reversible CO2 sorption processes in an apparently nonporous organic crystal under
Sean E Doris et al.
Journal of the American Chemical Society, 136(44), 15702-15710 (2014-10-11)
Cationic naked nanocrystals (NCs) are useful building units for assembling hierarchical mesostructured materials. Until now, their preparation required strongly electrophilic reagents that irreversibly sever bonds between native organic ligands and the NC surface. Colloidal instabilities can occur during ligand stripping

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