Direkt zum Inhalt
Merck
Alle Fotos(2)

Dokumente

697079

Sigma-Aldrich

Titantetrachlorid

packaged for use in deposition systems

Synonym(e):

Titan(IV)-chlorid, TTC, Titantetrachlorid

Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
Alle Fotos(2)

About This Item

Lineare Formel:
TiCl4
CAS-Nummer:
7550-45-0
Molekulargewicht:
189.68
EG-Nummer:
231-444-5
MDL-Nummer:
MFCD00011267
UNSPSC-Code:
12352103
PubChem Substanz-ID:
329761885
NACRES:
NA.23

Dampfdruck

50 mmHg ( 55 °C)
9.6 mmHg ( 20 °C)

Qualitätsniveau

100

Assay

≥99.995% (trace metals analysis)

Form

liquid

Eignung der Reaktion

core: titanium
reagent type: catalyst

bp

135-136 °C (lit.)

mp (Schmelzpunkt)

−25 °C (lit.)

Dichte

1.73 g/mL at 20 °C (lit.)

SMILES String

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChIKey

XJDNKRIXUMDJCW-UHFFFAOYSA-J

Suchen Sie nach ähnlichen Produkten? Aufrufen Leitfaden zum Produktvergleich

Verwandte Kategorien

Allgemeine Beschreibung

Atomic number of base material: 22 Titanium

Anwendung

Titanium tetrachloride may be used in the vapor synthesis of titania powder by oxidaition. It may be used as a catalyst in cross and asymmetric aldol reactions. Other possible uses of titanium tetrachloride is in the synthesis of :
  • γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds,
  • N-Phosphinoylimines and N-sulphonylimines from aromatic aldehydes,
  • Homoallyl ethers from allylsilanes and acetals.6

Piktogramme

Skull and crossbonesCorrosion
GHS06,GHS05

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 1 Inhalation - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Zielorgane

Respiratory system

Zusätzliche Gefahrenhinweise

EUH014

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

Besitzen Sie dieses Produkt bereits?

In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

New cross-aldol reactions. Reactions of silyl enol ethers with carbonyl compounds activated by titanium tetrachloride
Mukaiyama T, et al.
Journal of the American Chemical Society, 96(24), 7503-7509 null
The titanium tetrachloride induced synthesis of N-phosphinoylimines and N-sulphonylimines directly from aromatic aldehydes
Jennings WB and Lovely CJ
Tetrahedron, 47(29), 5561-5568 (1991)
M T Crimmins et al.
The Journal of organic chemistry, 66(3), 894-902 (2001-06-30)
Asymmetric aldol additions using chlorotitanium enolates of N-acyloxazolidinone, oxazolidinethione, and thiazolidinethione propionates proceed with high diastereoselectivity for the Evans or non-Evans syn product depending on the nature and amount of the base used. With 1 equiv of titanium tetrachloride and
Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride
Hosomi A and Sakurai H
Tetrahedron Letters, 17(16), 1295-1298 (1976)
Ravit Madar et al.
Brain, behavior, and immunity, 48, 301-312 (2015-05-30)
Neuroinflammation in the central nervous system is detrimental for learning and memory, as evident form epidemiological studies linking developmental defects and maternal exposure to harmful pathogens. Postnatal infections can also induce neuroinflammatory responses with long-term consequences. These inflammatory responses can
Alle zugehörigen Dokumente anzeigen

Artikel

The Savannah ALD System - An Excellent Tool for Atomic Layer Deposition

igma-Aldrich.com presents an article regarding the savannah ALD system - an excellent tool for atomic layer deposition.

Dye-Sensitized and Perovskite Solar Cells: Interface Engineering by Atomic Layer Deposition

Since the demonstration of the first practical solar cell 60 years ago, research on novel materials, improved solar cell design and structure, and innovative manufacturing processes have all contributed to a continuous increase in the efficiency of photovoltaic (PV) devices.

Atomic Layer Deposition of Nanomaterials for Li-Ion Batteries, Fuel Cells, and Solar Cells

Nanomaterials are considered a route to the innovations required for large-scale implementation of renewable energy technologies in society to make our life sustainable.

Nanowire Synthesis: From Top-Down to Bottom-Up

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

Unser Team von Wissenschaftlern verfügt über Erfahrung in allen Forschungsbereichen einschließlich Life Science, Materialwissenschaften, chemischer Synthese, Chromatographie, Analytik und vielen mehr..

Setzen Sie sich mit dem technischen Dienst in Verbindung.