692204

(R)-[(RuCl(SEGPHOS^®))₂(μ-Cl)₃][NH₂Me₂]

• Synonym(e): Dimethylammonium-dichlor-tri-(μ-chlor)-bis-[(R)-(+)-5,5′-bis-(diphenylphosphino)-4,4′-bi-1,3-benzodioxol]-diruthenat(II)
• Lineare Formel: (CH₃)₂NH₂+[C₇₆H₅₆Cl₅O₈P₄Ru₂]-
• CAS-Nummer: 346457-41-8
• Molekulargewicht: 1646.64
• MDL-Nummer: MFCD09753037
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329761474
• NACRES: NA.22

Eigenschaften

• Form: powder
• Lagertemp.: 2-8°C
• SMILES String: Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.C3Oc4ccc(P(c5ccccc5)c6ccccc6)c(c4O3)-c7c8OCOc8ccc7P(c9ccccc9)c%10ccccc%10.C%11Oc%12ccc(P(c%13ccccc%13)c%14ccccc%14)c(c%12O%11)-c%15c%16OCOc%16ccc%15P(c%17ccccc%17)c%18ccccc%18
• InChI: 1S/2C38H28O4P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;1-3-2;;;;;;;/h2*1-24H,25-26H2;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1
• InChIKey: RENFEASRVBXAEN-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

(R)-[(RuCl(SEGPHOS^®))₂(μ-Cl)₃][NH₂Me₂] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS^®, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.

Anwendung

Takasago Ligands and Complexes for Asymmetric Reactions

Rechtliche Hinweise

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136, 3549390

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable