668281

1-Hydroxytetraphenyl-cyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-Hydrotetracarbonyldiruthenium(II)

98%

• Synonym(e): 2,3,4,5-Tetraphenyl-2,4-cyclopentadien-1-on Rutheniumkomplex, Shvo-Katalysator, Tetracarbonyl-μ-hydro[(1,2,3,4,5-h)-1-hydroxylat-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl][(1,2,3,4,5-h)-1-hydroxy-2,3,4,5-tetraphenyl-2,4-cyclopentadien-1-yl]-diruthenium
• Empirische Formel (Hill-System): C₆₂H₄₂O₆Ru₂
• CAS-Nummer: 104439-77-2
• Molekulargewicht: 1085.13
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24884974
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Form: solid
• Eignung der Reaktion: core: ruthenium; reagent type: catalyst
• mp (Schmelzpunkt): 223-227 °C
• SMILES String: [Ru][RuH].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O[C]1[C]([C]([C]([C]1c2ccccc2)c3ccccc3)c4ccccc4)c5ccccc5.O=C6C(c7ccccc7)=C(c8ccccc8)C(c9ccccc9)=C6c%10ccccc%10
• InChI: 1S/C29H21O.C29H20O.4CO.2Ru.H/c2*30-29-27(23-17-9-3-10-18-23)25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(29)24-19-11-4-12-20-24;4*1-2;;;/h1-20,30H;1-20H;;;;;;;
• InChIKey: PISMVXYUJBWZFB-UHFFFAOYSA-N

Beschreibung

Anwendung

Shvo′s Catalyst

Has found numerous applications as a versatile catalyst in organic synthesis, including the reduction of aldehydes and ketones to alcohols, bimolecular disproportionation reaction of aldehydes to esters, isomerization of allylic alcohols and oxidation of alcohols.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable