665029

1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)imidazolinium-Chlorid

• Synonym(e): 1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium-chlorid
• Empirische Formel (Hill-System): C₂₂H₃₁ClN₂
• CAS-Nummer: 639820-61-4
• Molekulargewicht: 358.95
• MDL-Nummer: MFCD08276859
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24884707
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Eignung der Reaktion: reagent type: catalyst; reaction type: Ring-Opening Polymerization
• mp (Schmelzpunkt): 263-280 °C
• SMILES String: [Cl-].Cc1cc(C)c(N2CC[N+](=C2)C34CC5CC(CC(C5)C3)C4)c(C)c1
• InChI: 1S/C22H31N2.ClH/c1-15-6-16(2)21(17(3)7-15)23-4-5-24(14-23)22-11-18-8-19(12-22)10-20(9-18)13-22;/h6-7,14,18-20H,4-5,8-13H2,1-3H3;1H/q+1;/p-1/t18-,19+,20-,22-;
• InChIKey: MJOMRTQWLPXDJQ-ZFCGJYDVSA-M

Beschreibung

Anwendung

Reactant for:

• Preparation of chelated ruthenium alkoxybenzylidene imidazolidene carbene pivalate catalysts for Z-selective olefin metathesis
• Use in ring-opening metathesis polymerization and ring-closing metathesis reactions via Grubbs catalyst mediated reactions
• Preparation of adamantyl-substituted N-heterocyclic carbene ligands in second-generation Grubbs-type iridium metathesis catalysis

Rechtliche Hinweise

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves