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Merck

592684

Sigma-Aldrich

Bis(dimethylphosphin)methan

97%

Synonym(e):

DMPM

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About This Item

Lineare Formel:
(CH3)2PCH2P(CH3)2
CAS-Nummer:
Molekulargewicht:
136.11
MDL-Nummer:
UNSPSC-Code:
12352001
PubChem Substanz-ID:
NACRES:
NA.22

Qualitätsniveau

Assay

97%

Eignung der Reaktion

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Brechungsindex

n20/D 1.5060 (lit.)

bp

42 °C/12 mmHg (lit.)

Dichte

0.86 g/mL at 25 °C (lit.)

Funktionelle Gruppe

phosphine

SMILES String

CP(C)CP(C)C

InChI

1S/C5H14P2/c1-6(2)5-7(3)4/h5H2,1-4H3

InChIKey

MRNJHNUEBDGNEL-UHFFFAOYSA-N

Anwendung

Reactant for:
  • Preparation of ruthenium carbonyl hydrido phosphanido diphosphine dinuclear complexes
  • Luminescent face-to-face dinuclear platinum(II) alkynyl phosphine complexes
  • Phosphorus-phosphorus bond and nuclear spin-spin coupling
  • Formation of a catalytic ruthenium(II)-triphos complex

Catalyst for:
  • Asymmetric alkylation of racemic secondary phosphines
  • Palladium-diphosphine catalyzed carbonylation of ethene

Piktogramme

Flame

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Pyr. Liq. 1

Lagerklassenschlüssel

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Graziella Cimino-Reale et al.
Journal of hematology & oncology, 10(1), 140-140 (2017-07-19)
Understanding the molecular/cellular underpinnings of diffuse malignant peritoneal mesothelioma (DMPM), a fatal malignancy with limited therapeutic options, is of utmost importance for the fruitful management of the disease. In this context, we previously found that telomerase activity (TA), which accounts
Jana Elias et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(26), 6553-6561 (2019-03-02)
A new boron-boron dehydrocoupling strategy was established, providing convenient access to some diborane(4) compounds starting from simple borane adducts under mild conditions. In contrast to the traditional pathway using a reducing reagent, the reduction from BIII to BII was paradoxically
Giovanna Li Petri et al.
British journal of cancer, 123(4), 644-656 (2020-06-05)
Expression of proton-coupled folate transporter (PCFT) is associated with survival of mesothelioma patients treated with pemetrexed, and is reduced by hypoxia, prompting studies to elucidate their correlation. Modulation of glycolytic gene expression was evaluated by PCR arrays in tumour cells
Michelandrea De Cesare et al.
Oncotarget, 6(15), 13119-13132 (2015-05-08)
Survivin, which is highly expressed and promotes cell survival in diffuse malignant peritoneal mesothelioma (DMPM), exclusively relies on exportin 1 (XPO1/CRM1) to be shuttled into the cytoplasm and perform its anti-apoptotic function. Here, we explored the efficacy of Selective Inhibitors

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