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Sigma-Aldrich

Molybdänhexacarbonyl

≥99.9% trace metals basis

Synonym(e):

Hexacarbonylmolybdän

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About This Item

Lineare Formel:
Mo(CO)6
CAS-Nummer:
13939-06-5
Molekulargewicht:
264.00
EG-Nummer:
237-713-3
MDL-Nummer:
MFCD00003466
UNSPSC-Code:
12352300
PubChem Substanz-ID:
24880893
NACRES:
NA.23

Dampfdichte

9.1 (vs air)

Qualitätsniveau

100

Assay

≥99.9% trace metals basis

Form

solid
solid

Aufgereinigt durch

sublimation

Eignung der Reaktion

core: molybdenum
reagent type: catalyst

bp

156 °C (lit.)

mp (Schmelzpunkt)

150 °C (dec.) (lit.)

Dichte

1.96 g/mL at 25 °C (lit.)

SMILES String

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

InChIKey

KMKBZNSIJQWHJA-UHFFFAOYSA-N

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Verwandte Kategorien

Allgemeine Beschreibung

Atomic number of base material: 42 Molybdenum

Piktogramme

Skull and crossbones
GHS06

Signalwort

Danger

H-Sätze

H331

Gefahreneinstufungen

Acute Tox. 3 Inhalation

Lagerklassenschlüssel

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Analysenzertifikate (COA)

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In situ generation of carbon monoxide from solid molybdenum hexacarbonyl. A convenient and fast route to palladium-catalyzed carbonylation reactions.
Nils-Fredrik K Kaiser et al.
Journal of combinatorial chemistry, 4(2), 109-111 (2002-03-12)
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in
Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative
Microwave-promoted aminocarbonylations of aryl chlorides using Mo(CO)(6) as a solid carbon monoxide source.
Olof Lagerlund et al.
Journal of combinatorial chemistry, 8(1), 4-6 (2006-01-10)
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