459852
9,10-Anthracendicarbonitril
97%
Synonym(e):
9,10-Dicyan-anthracen
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Alle Fotos(1)
About This Item
Empirische Formel (Hill-System):
C16H8N2
CAS-Nummer:
Molekulargewicht:
228.25
Beilstein:
1646384
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Assay
97%
mp (Schmelzpunkt)
340 °C (lit.)
SMILES String
N#Cc1c2ccccc2c(C#N)c3ccccc13
InChI
1S/C16H8N2/c17-9-15-11-5-1-2-6-12(11)16(10-18)14-8-4-3-7-13(14)15/h1-8H
InChIKey
BIOPPFDHKHWJIA-UHFFFAOYSA-N
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Verwandte Kategorien
Allgemeine Beschreibung
9,10-Anthracenedicarbonitrile (DCA, ADC) is an anthracene derivative. Photochemical reactions of DCA in MeCN-MeOH or MeCN-H2O containing hydroxides or methoxides affords 9-methylimino-10-anthracenecarbonitrile. It participates in the generation of nucleophilic α-hydroxymethyl radicals from α-silyl ethers by irradiation. Binding energy of 9,10-anthracenedicarbonitrile adsorbed onto graphene is -1.23eV.
Anwendung
9,10-Anthracenedicarbonitrile may be used as photosensitizer to investigate the photoisomerization of trans-stilbene (TS) in sodium dodecyl sulfate (SDS)/benzyl alcohol (BA)/H2O system.
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves, type N95 (US)
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a-Silyl Ethers as Hydroxymethyl Anion Equivalents in Photoinduced Radical Electron Transfer Additions.
Gutenberger G, et al.
Angewandte Chemie (International Edition in English), 37(5), 660-662 (1998)
Photoinduced Bimolecular Electron Transfer from Cyano Anions in Ionic Liquids.
Boning W, et al.
The Journal of Physical Chemistry B, 119, 14790-14799 (2015)
Xia Guo et al.
Journal of colloid and interface science, 283(2), 578-584 (2005-02-22)
Photoisomerization of trans-stilbene (TS) was investigated in sodium dodecyl sulfate (SDS)/benzyl alcohol (BA)/H(2)O systems in order to establish the relationship between the reaction yields and the compositions and structures of molecular organized assemblies. The results show that, in SDS/BA/H(2)O systems
Steven Bailey et al.
The Journal of chemical physics, 140(5), 054708-054708 (2014-02-12)
To identify families of stable planar anchor groups for use in single molecule electronics, we report detailed results for the binding energies of two families of anthracene and pyrene derivatives adsorbed onto graphene. We find that all the selected derivatives
The photochemical reactions of 9, 10-anthracenedicarbonitrile and 1, 4-naphthalenedicarbonitrile in acetonitrile in the presence of bases.
Freccero M, et al.
Tetrahedron, 50(7), 2115-2130 (1994)
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