456705

(DHQ)₂AQN

95%

• Synonym(e): Hydrochinin-(anthrachinon-1,4-diyl)-diether
• Empirische Formel (Hill-System): C₅₄H₅₆N₄O₆
• CAS-Nummer: 176097-24-8
• Molekulargewicht: 857.05
• MDL-Nummer: MFCD00467215
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329756884
• NACRES: NA.22

Eigenschaften

• Assay: 95%
• Form: solid
• Optische Aktivität: [α]20/D +495°, c = 1 in chloroform
• mp (Schmelzpunkt): 175-180 °C (lit.)
• Funktionelle Gruppe: ketone
• SMILES String: CC[C@@H]1CN2CC[C@H]1C[C@@H]2[C@H](Oc3ccc(O[C@@H]([C@H]4C[C@@H]5CCN4C[C@H]5CC)c6ccnc7ccc(OC)cc67)c8C(=O)c9ccccc9C(=O)c38)c%10ccnc%11ccc(OC)cc%10%11
• InChI: 1S/C54H56N4O6/c1-5-31-29-57-23-19-33(31)25-45(57)53(39-17-21-55-43-13-11-35(61-3)27-41(39)43)63-47-15-16-48(50-49(47)51(59)37-9-7-8-10-38(37)52(50)60)64-54(46-26-34-20-24-58(46)30-32(34)6-2)40-18-22-56-44-14-12-36(62-4)28-42(40)44/h7-18,21-22,27-28,31-34,45-46,53-54H,5-6,19-20,23-26,29-30H2,1-4H3/t31-,32-,33+,34+,45-,46-,53-,54-/m1/s1
• InChIKey: ARCFYUDCVYJQRN-KGHNJIHGSA-N

Beschreibung

Anwendung

Superior ligand for asymmetric dihydroxylation reactions of most olefins bearing aliphatic substituents or olefins having heteroatoms in the allylic position.

Rechtliche Hinweise

Sold under license from Rhodia Pharma Solutions.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves