406139

Chlordicyclohexylboran

98%

• Synonym(e): Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane
• Lineare Formel: (C₆H₁₁)₂BCl
• CAS-Nummer: 36140-19-9
• Molekulargewicht: 212.57
• MDL-Nummer: MFCD00191906
• UNSPSC-Code: 12352106
• PubChem Substanz-ID: 24865357

Eigenschaften

• Assay: 98%
• Form: liquid
• Eignung der Reaktion: reagent type: reductant
• bp: 100-101 °C/1 mmHg (lit.)
• Dichte: 0.97 g/mL at 25 °C (lit.)
• SMILES String: ClB(C1CCCCC1)C2CCCCC2
• InChI: 1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2
• InChIKey: PBBOKJIYEZCTEH-UHFFFAOYSA-N

Beschreibung

Anwendung

A convenient reagent for regio- and stereoselective enolboration of ketones and other carbonyl derivatives.

Reactant for:

• Aldol addition reactions
• Mukaiyama aldol addition
• Microwave assisted ring closing metathesis reactions
• C-alkylation of aromatic aldimines
• Reversible ketone-ketone aldol reactions
• Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

Sicherheitshinweise

• Piktogramme: GHS02,GHS05
• Signalwort: Danger
• H-Sätze: H250,H314
• P-Sätze: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P370 + P378
• Gefahreneinstufungen: Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): No data available
• Flammpunkt (°C): No data available