394262

Octadecylmagnesiumchlorid -Lösung

0.5 M in THF

• Synonym(e): Chlorooctadecylmagnesium, Octadecane, magnesium complex
• Lineare Formel: CH₃(CH₂)₁₇MgCl
• CAS-Nummer: 116980-66-6
• Molekulargewicht: 313.24
• MDL-Nummer: MFCD00012233
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24864583
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: reaction type: Grignard Reaction
• Konzentration: 0.5 M in THF
• bp: 67 °C
• Dichte: 0.906 g/mL at 25 °C
• SMILES String: CCCCCCCCCCCCCCCCCC[Mg]Cl
• InChI: 1S/C18H37.ClH.Mg/c1-3-5-7-9-11-13-15-17-18-16-14-12-10-8-6-4-2;;/h1,3-18H2,2H3;1H;/q;;+1/p-1
• InChIKey: ONJPXWZQVLKGIU-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

Octadecylmagnesium chloride is a Grignard reagent commonly used in organic synthesis for various transformations, including nucleophilic addition reactions and carbon-carbon bond formation via palladium-catalyzed alkylation and arylation reactions.

Anwendung

Octadecylmagnesium chloride can be used for the introduction of octyl substituents on the bipyridine skeletons to prepare functionalized 4,4′-bipyridines, which are used as linkers formation of discrete metal complexes.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H302,H314,H335,H351
• P-Sätze: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 1
• Flammpunkt (°F): -4.0 °F - closed cup
• Flammpunkt (°C): -20 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter