376159

(Trimethylsilyl)methylisocyanid

97%

• Synonym(e): Isocyanomethyl-trimethylsilan
• Lineare Formel: (CH₃)₃SiCH₂NC
• CAS-Nummer: 30718-17-3
• Molekulargewicht: 113.23
• Beilstein: 3930556
• MDL-Nummer: MFCD00043056
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24863423
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 97%
• Form: liquid
• Brechungsindex: n20/D 1.416 (lit.)
• bp: 52-53 °C/35 mmHg (lit.)
• Dichte: 0.803 g/mL at 25 °C (lit.)
• Lagertemp.: −20°C
• SMILES String: C[Si](C)(C)C[N+]#[C-]
• InChI: 1S/C5H11NSi/c1-6-5-7(2,3)4/h5H2,2-4H3
• InChIKey: OLSTVZKPVGMQKB-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Synthesis of (trimethylsilyl)methyl isocyanide and its reaction with protic nucleophiles has been reported. An improved preparation of (trimethylsilyl)methyl isocyanide is reported. Reaction of (trimethylsilyl)methyl isocyanide with (η²-formaldehyde)zirconocene complex is reported to yield insertion products.

Anwendung

(Trimethylsilyl)methyl isocyanide may be used in the preparation of isocyanomethylenetriphenylphosphorane.

Verpackung

Bottomless glass bottle. Contents are inside inserted fused cone.

Sicherheitshinweise

• Piktogramme: GHS02,GHS06
• Signalwort: Danger
• H-Sätze: H225,H301 + H311 + H331
• P-Sätze: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311
• Gefahreneinstufungen: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): <59.0 °F - closed cup
• Flammpunkt (°C): < 15 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter