360899

Malonsäure-monoethylester Kaliumsalz

98%

• Synonym(e): Kalium-monoethyl-malonat
• Lineare Formel: C₂H₅OCOCH₂CO₂K
• CAS-Nummer: 6148-64-7
• Molekulargewicht: 170.20
• Beilstein: 3721682
• EG-Nummer: 228-156-7
• MDL-Nummer: MFCD00035603
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24862007
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 98%
• Form: solid
• mp (Schmelzpunkt): 194 °C (dec.) (lit.)
• Funktionelle Gruppe: ester
• SMILES String: [K+].CCOC(=O)CC([O-])=O
• InChI: 1S/C5H8O4.K/c1-2-9-5(8)3-4(6)7;/h2-3H2,1H3,(H,6,7);/q;+1/p-1
• InChIKey: WVUCPRGADMCTBN-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

Ethyl potassium malonate (potassium ethyl malonate) reacts with aryl nitriles in the presence of zinc chloride and a catalytic amount of Hünig′s base to yield β-amino acrylates. Ethyl potassium malonate is formed as an intermediate during the synthesis of ethyl tert-butyl malonate.

Anwendung

Ethyl potassium malonate (potassium ethyl malonate) may be used to generate (trimethylsilyl)ethyl malonate in situ, which can be acylated to prepare a variety of β-ketoesters or alkylidene malonates.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 2
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves