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283606

Sigma-Aldrich

Palladium(II)-chlorid -Lösung

5 wt. % in 10 wt. % HCl

Synonym(e):

Dichloropalladium, Palladium dichloride, Palladous chloride

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About This Item

Lineare Formel:
PdCl2
CAS-Nummer:
7647-10-1
Molekulargewicht:
177.33
MDL-Nummer:
MFCD00003558
UNSPSC-Code:
12161600
PubChem Substanz-ID:
24857119
NACRES:
NA.22

Form

liquid

Eignung der Reaktion

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Konzentration

5 wt. % in 10 wt. % HCl

Dichte

1.06 g/mL at 25 °C

SMILES String

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChIKey

PIBWKRNGBLPSSY-UHFFFAOYSA-L

Verwandte Kategorien

Allgemeine Beschreibung

Palladium(II) chloride is a representative salt of Pd(II) that is used as a precursor to prepare palladium catalysts for various reactions, such as Heck coupling, Suzuki coupling, Sonagashira coupling, and Buchwald-Hartwig coupling. It is also used as an oxidizing agent.

Anwendung

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.

Signalwort

Danger

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

Lagerklassenschlüssel

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
MKCM4401
MKCL4190
MKCK6308
MKCH2356
MKCF4529

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Die Dokumentenbibliothek aufrufen

Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Annesofie Faurschou et al.
Contact dermatitis, 64(4), 185-195 (2011-03-12)
Consumers are mainly exposed to palladium from jewellery and dental restorations. Palladium contact allergy is nearly always seen together with nickel allergy, as palladium and nickel tend to cross-react. We aimed to analyse the available palladium patch test data and
Qianying Xu et al.
Analytica chimica acta, 707(1-2), 114-120 (2011-10-27)
In pH 1.7-3.5 acid medium, palladium chloride could react with adenine (A) to form a ternary complex of [PdCl(2)·A], which would self-aggregate to form uniformly dispersed nanoparticles-[PdCl(2)·A](n) with an average size of 42 nm through the squeezing effect of aqueous
Gábor Kovács et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5612-5619 (2012-03-31)
First-principles molecular dynamics coupled with metadynamics have been used to gain a deeper insight into the reaction mechanism of the Wacker process by determining the nature of the active species. An explicit and dynamic representation of the aqueous solvent, which
Agnieszka Krogul et al.
Dalton transactions (Cambridge, England : 2003), 41(2), 658-666 (2011-11-10)
Palladium(II) complexes attract great attention due to their remarkable catalytic and biological activity. In the present study X-ray characterization, UV-Vis and Time-Dependent Density Functional Theory (TD-DFT) calculations for six PdCl(2)(XPy)(2) complexes (where: Py = pyridine; X = H, CH(3) or
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