270822

Di-tert-butylacetylendicarboxylat

98%

• Synonym(e): 2-Butindisäure-di-tert.-butylester, Di-tert.-butyl-acetylendicarboxylat
• Lineare Formel: (CH₃)₃COCOC≡CCOOC(CH₃)₃
• CAS-Nummer: 66086-33-7
• Molekulargewicht: 226.27
• Beilstein: 1957547
• EG-Nummer: 266-135-4
• MDL-Nummer: MFCD00008808
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24856403
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 98%
• Form: solid
• bp: 80-82 °C/0.05 mmHg (lit.)
• mp (Schmelzpunkt): 33-37 °C (lit.)
• Funktionelle Gruppe: ester
• SMILES String: CC(C)(C)OC(=O)C#CC(=O)OC(C)(C)C
• InChI: 1S/C12H18O4/c1-11(2,3)15-9(13)7-8-10(14)16-12(4,5)6/h1-6H3
• InChIKey: FBCRUXRGQFLOMC-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

The cross-cyclotrimerization of di-tert-butyl acetylenedicarboxylate, silylacetylenes and acrylamides was studied with cationic rhodium(I)/(R)-tol-binap complex as catalyst. Glycosyl azides were subjected to 1,3-dipolar cycloaddition with di-tert-butyl acetylenedicarboxylate.

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H314,H335
• P-Sätze: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges