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Dokumente

266086

Sigma-Aldrich

Kupfer

powder, <425 μm, 99.5% trace metals basis

Synonym(e):

Cu

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About This Item

Empirische Formel (Hill-System):
Cu
CAS-Nummer:
7440-50-8
Molekulargewicht:
63.55
EG-Nummer:
231-159-6
MDL-Nummer:
MFCD00010965
UNSPSC-Code:
12141711
PubChem Substanz-ID:
24856123
NACRES:
NA.22

Assay

99.5% trace metals basis

Form

powder

Eignung der Reaktion

core: copper
reagent type: catalyst

Widerstandsfähigkeit

1.673 μΩ-cm, 20°C

Partikelgröße

<425 μm

bp

2567 °C (lit.)

mp (Schmelzpunkt)

1083.4 °C (lit.)

Dichte

8.94 g/mL at 25 °C (lit.)

SMILES String

[Cu]

InChI

1S/Cu

InChIKey

RYGMFSIKBFXOCR-UHFFFAOYSA-N

Anwendung

Catalyst for the cyclization and coupling reactions; e.g. Ullmann coupling reactions, preparation of cyclopropanes, decomposition of diazoketones or diazoesters, insertion to C-O bonds, [3 + 2] cycloaddition of terminal alkynes and azides, hydrogenation.

Piktogramme

FlameEnvironment
GHS02,GHS09

Signalwort

Danger

H-Sätze

H228,H410

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Sol. 1

Lagerklassenschlüssel

4.1B - Flammable solid hazardous materials

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Analysenzertifikate (COA)

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Seiko Ishida et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(48), 19507-19512 (2013-11-13)
Copper is an essential trace element, the imbalances of which are associated with various pathological conditions, including cancer, albeit via largely undefined molecular and cellular mechanisms. Here we provide evidence that levels of bioavailable copper modulate tumor growth. Chronic exposure
R Squitti et al.
Neurology, 67(1), 76-82 (2006-07-13)
To assess whether serum copper in Alzheimer disease (AD) correlates with cognitive scores, beta-amyloid, and other CSF markers of neurodegeneration. The authors studied copper, ceruloplasmin, total peroxide, and antioxidants levels (TRAP) in serum; beta-amyloid in plasma; and copper, beta-amyloid, h-tau
Magnus Andersson et al.
Nature structural & molecular biology, 21(1), 43-48 (2013-12-10)
Heavy metals in cells are typically regulated by PIB-type ATPases. The first structure of the class, a Cu(+)-ATPase from Legionella pneumophila (LpCopA), outlined a copper transport pathway across the membrane, which was inferred to be occluded. Here we show by
Hiroshi Sato et al.
Science (New York, N.Y.), 343(6167), 167-170 (2013-12-18)
Carbon monoxide (CO) produced in many large-scale industrial oxidation processes is difficult to separate from nitrogen (N2), and afterward, CO is further oxidized to carbon dioxide. Here, we report a soft nanoporous crystalline material that selectively adsorbs CO with adaptable
Stephen G Kaler et al.
The New England journal of medicine, 358(6), 605-614 (2008-02-08)
Menkes disease is a fatal neurodegenerative disorder of infancy caused by diverse mutations in a copper-transport gene, ATP7A. Early treatment with copper injections may prevent death and illness, but presymptomatic detection is hindered by the inadequate sensitivity and specificity of
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