242934

Iodessigsäure-ethylester

98%

• Synonym(e): Ethyl 2-iodoacetate, Ethyl monoiodoacetate, Iodoacetic acid ethyl ester
• Lineare Formel: ICH₂COOC₂H₅
• CAS-Nummer: 623-48-3
• Molekulargewicht: 214.00
• Beilstein: 741934
• EG-Nummer: 210-796-3
• MDL-Nummer: MFCD00001081
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24854592
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 98%
• Brechungsindex: n20/D 1.503 (lit.)
• bp: 179-180 °C (lit.)
• Dichte: 1.808 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: ester; iodo
• Lagertemp.: 2-8°C
• SMILES String: CCOC(=O)CI
• InChI: 1S/C4H7IO2/c1-2-7-4(6)3-5/h2-3H2,1H3
• InChIKey: MFFXVVHUKRKXCI-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Ethyl iodoacetate, also known as iodoacetic acid ethyl ester, serves as an alkylating agent and a radical precursor in organic synthesis. It is also commonly used as a lachrymatory agent.

Anwendung

Ethyl iodoacetate was used in the synthesis of trans-2,3-disubstituted indolines by reacting with 1-azido-2-allylbenzene derivatives via a diastereoselective radical cascade.

Sicherheitshinweise

• Piktogramme: GHS06,GHS05
• Signalwort: Danger
• H-Sätze: H300,H314
• P-Sätze: P280 - P301 + P310 + P330 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 + P310
• Gefahreneinstufungen: Acute Tox. 2 Oral - Eye Dam. 1 - Skin Corr. 1B
• Lagerklassenschlüssel: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 170.6 °F - closed cup
• Flammpunkt (°C): 77 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter