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Wichtige Dokumente
240761
1-Hexen
≥99%
Synonym(e):
1-n-Hexene
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About This Item
Lineare Formel:
CH3(CH2)3CH=CH2
CAS-Nummer:
Molekulargewicht:
84.16
Beilstein:
1209240
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Dampfdichte
3 (vs air)
Qualitätsniveau
Dampfdruck
155 mmHg ( 21.1 °C)
Assay
≥99%
Form
liquid
Selbstzündungstemp.
487 °F
Brechungsindex
n20/D 1.388 (lit.)
bp
60-66 °C (lit.)
Dichte
0.678 g/mL at 25 °C (lit.)
Funktionelle Gruppe
allyl
SMILES String
CCCCC=C
InChI
1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3
InChIKey
LIKMAJRDDDTEIG-UHFFFAOYSA-N
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Allgemeine Beschreibung
The kinetics of polymerization of 1-hexene was studied using a family of five zirconium amine bis-phenolate catalysts. Polymerization reaction of 1-hexene catalyzed by a series of hafnium complexes was studied.
Anwendung
- 1-Hexene in High Molecular Weight Polymer Synthesis: The synthesis of high molecular weight copolymers from 1-hexene and methyl acrylate using Lewis acid catalysts showcased advanced applications in materials science, specifically in developing durable and versatile polymer materials (Wan et al., 2024).
- 1-Hexene′s Role in Proton-Exchange Membrane Enhancement: Utilizing 1-hexene in the structural characterization and enhancement of physicochemical properties of functionally porous proton-exchange membranes highlights its critical role in improving energy efficiency and performance in fuel cell technologies (Ponomar et al., 2024).
Signalwort
Danger
H-Sätze
Gefahreneinstufungen
Asp. Tox. 1 - Flam. Liq. 2
Zusätzliche Gefahrenhinweise
Lagerklassenschlüssel
3 - Flammable liquids
WGK
WGK 2
Flammpunkt (°F)
-13.0 °F - closed cup
Flammpunkt (°C)
-25.0 °C - closed cup
Persönliche Schutzausrüstung
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Takahiro Yasumoto et al.
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Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
D Keith Steelman et al.
Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
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The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
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