908800

1,2-Bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate

Umicore

• Synonyme(s) : (R,R)-Et-DUPHOS-Rh
• Formule empirique (notation de Hill): C₃₀H₄₈BF₄P₂Rh
• Numéro CAS: 228121-39-9
• Poids moléculaire : 660.36
• Code UNSPSC : 12352005
• Nomenclature NACRES : NA.22

Propriétés

• Forme: powder
• Chaîne SMILES: C[CH+]C.CC[C@@H]1CC[C@@H](CC)P12C3=C(P4([Rh](C)2C)[C@H](CC)CC[C@H]4CC)C=CC=C3.FB(F)F.C5C/C=C\CC/C=C\5.[F-]
• InChI: 1S/C22H36P2.C8H12.BF4.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;+1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m1.../s1
• Clé InChI: DSYBEQKPSKLNMC-KYOOHHHUSA-N

Description

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:

• Asymmetric hydrogenation reactions

Chiralyst Rh660 is a homogeneous catalyst useful for asymmetric reactions and asymmetric hydrogenation.
The catalyst works well with privileged ligands.

Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083)

Stockage et stabilité

Do not store above 25°C (77°F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.

Informations légales

Product of Umicore

Additional information available at www.pmc.umicore.com

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable