00375

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

purum, ≥98.0% (HPLC)

• Formule empirique (notation de Hill): C₁₁H₂₁N₂O₂
• Numéro CAS: 14691-89-5
• Poids moléculaire : 213.30
• Numéro Beilstein : 3546225
• Numéro CE : 423-840-3
• Numéro MDL: MFCD00043593
• Code UNSPSC : 12352005
• ID de substance PubChem : 329747053
• Nomenclature NACRES : NA.22

Propriétés

• Qualité: purum
• Niveau de qualité: 200
• Pureté: ≥98.0% (HPLC)
• Score du produit alternatif plus écologique: old score: 9; new score: 8; Find out more about DOZN™ Scoring
• Caractéristiques du produit alternatif plus écologique: Waste Prevention; Safer Solvents and Auxiliaries; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• Pf: 143-145 °C (lit.); 143-146 °C
• Autre catégorie plus écologique: , Re-engineered
• Température de stockage: 2-8°C
• Chaîne SMILES: CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
• InChI: 1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
• Clé InChI: UXBLSWOMIHTQPH-UHFFFAOYSA-N

Description

Description générale

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by ¹H, ¹³C and ¹⁵N NMR spectral data.

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Inherently Safer Chemistry for Accident Prevention”. Click here to view its DOZN scorecard.

Application

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

Autres remarques

New oxidant for the mild oxidation of alcohols to carbonyls

Informations sur la sécurité

• Pictogrammes: GHS07
• Mention d'avertissement: Warning
• Mentions de danger: H302
• Conseils de prudence: P264 - P270 - P301 + P312 + P330 - P501
• Classification des risques: Acute Tox. 4 Oral
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: dust mask type N95 (US), Eyeshields, Gloves