901742

Dimethyl[(1-pyrrolidinyl)phenyl]-amine nickel(II) chloride

≥95%

• Synonyme(s) : (^PyrN^MeNN)Ni-Cl, (SP-4-4)-Chloro[N₁,N₁-dimethyl-N₂-[2-(1-pyrrolidinyl-κN)phenyl]-1,2-benzenediaminato-κN₁,κN₂]nickel, Second-generation Nickamine
• Formule empirique (notation de Hill): C₁₈H₂₂ClN₃Ni
• Poids moléculaire : 374.53
• Code UNSPSC : 12352101

Propriétés

• Pureté: ≥95%
• Forme: powder or crystals
• Pertinence de la réaction: core: nickel; reagent type: catalyst
• Chaîne SMILES: CN(C)C1=C(C=CC=C1)NC2=CC=CC=C2N3CCCC3.[Ni].Cl

Description

Application

As reported by Xile Hu′s lab, this nickel(II) pincer complex is an improvement from the first-generation Nickamine as an efficient Ni catalyst for Kumada and Suzuki-Miyaura cross-coupling of both nonactivated primary and secondary alkyl halides.

Autres remarques

From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides

A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions

Informations sur la sécurité

• Code de la classe de stockage: 13 - Non Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable