722057

4′-Hydroxy-3′-iodoacetophenone

97%

• Synonyme(s) : 1-(4-Hydroxy-3-iodophenyl)ethanone, 2-Iodo-4-acetylphenol, 3-Iodo-4-hydroxyacetophenone, 4-Acetyl-2-iodophenol
• Formule empirique (notation de Hill): C₈H₇IO₂
• Numéro CAS: 62615-24-1
• Poids moléculaire : 262.04
• Numéro MDL: MFCD06200221
• Code UNSPSC : 12352100
• ID de substance PubChem : 329763892
• Nomenclature NACRES : NA.22

Propriétés

• Niveau de qualité: 100
• Pureté: 97%
• Forme: powder
• Pf: 155-160 °C
• Groupe fonctionnel: iodo; ketone
• Chaîne SMILES: CC(=O)c1ccc(O)c(I)c1
• InChI: 1S/C8H7IO2/c1-5(10)6-2-3-8(11)7(9)4-6/h2-4,11H,1H3
• Clé InChI: SJRAJHOOMLHHQN-UHFFFAOYSA-N

Description

Application

Reactant for:

• Preparation of cyclopentene fused benzofurans and indoles via Pd-catalyzed tandem ring opening-ring closing reaction with diazabicyclic alkenes
• Highly regioselective synthesis of spirocyclic compounds by a palladium-catalyzed intermolecular tandem reaction
• Regioselective synthesis of indene derivatives via Pd/C-catalyzed cyclization reaction in air
• Preparation of carbazoles via cross-coupling with silylaryl triflates followed by palladium-catalyzed cyclization
• Stereoselective preparation of heteropolycyclic compounds via palladium-catalyzed stereoselective heteroannulation of with cyclic alkenes
• Preparation of disubstituted coumarins via palladium-catalyzed carbonylative annulation of internal alkynes
• Preparation of arylalkynes, benzofurans and indoles via Sonogashira coupling and cyclization on alumina

Informations sur la sécurité

• Pictogrammes: GHS05,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H302,H318
• Conseils de prudence: P264 - P270 - P280 - P301 + P312 - P305 + P351 + P338 - P501
• Classification des risques: Acute Tox. 4 Oral - Eye Dam. 1
• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable