388076

tert-Butyl peracetate solution

50 wt. % in odorless mineral spirits

• Synonyme(s) : tert -Butyl peracetate, tert -Butyl peroxyacetate
• Formule linéaire : CH₃CO₃C(CH₃)₃
• Numéro CAS: 107-71-1
• Poids moléculaire : 132.16
• Numéro MDL: MFCD00048240
• Code UNSPSC : 12162002
• ID de substance PubChem : 24864203
• Nomenclature NACRES : NA.23

Propriétés

• Forme: liquid
• t1/2: 10 hr(101 °C, 0.2 M in benzene)
• Concentration: 50 wt. % in odorless mineral spirits
• Indice de réfraction: n20/D 1.412
• Densité: 0.828 g/mL at 25 °C
• Chaîne SMILES: CC(=O)OOC(C)(C)C
• InChI: 1S/C6H12O3/c1-5(7)8-9-6(2,3)4/h1-4H3
• Clé InChI: SWAXTRYEYUTSAP-UHFFFAOYSA-N

Description

Application

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.

Reagent used as a methyl-radical source under photoredox catalysis in conjunction with photocatalyst [Ir{dF(CF₃)ppy}₂(dtbpy)]PF₆ (Aldrich L511765) for late-stage functionalization of biologically active heterocycles.

Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Informations sur la sécurité

• Pictogrammes: GHS02,GHS08,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H226,H242,H302,H304,H315,H319,H335,H336,H340,H350
• Conseils de prudence: P210 - P280 - P301 + P310 - P331 - P370 + P378 - P403 + P235
• Classification des risques: Acute Tox. 4 Oral - Asp. Tox. 1 - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 3 - Muta. 1B - Org. Perox. C - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Central nervous system, Respiratory system
• Code de la classe de stockage: 5.2 - Organic peroxides and self-reacting hazardous materials
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 98.6 °F - closed cup
• Point d'éclair (°C): 37 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter