- Blocking bimolecular activation pathways leads to different regioselectivity in metal-organic framework catalysis.
Blocking bimolecular activation pathways leads to different regioselectivity in metal-organic framework catalysis.
Chemical communications (Cambridge, England) (2012-07-28)
Teng Zhang, Feijie Song, Wenbin Lin
PMID22836205
RESUMO
Chiral metal-organic frameworks built from a Co-salen derived dicarboxylate bridging ligand exhibited different regioselectivities from the corresponding homogeneous catalyst by shutting down bimolecular activation pathways.
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