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Palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates.

Organic & biomolecular chemistry (2011-09-23)
Ru Chen, Saiwen Liu, Xinhua Liu, Luo Yang, Guo-Jun Deng
RESUMO

A palladium-catalyzed desulfitative C-H arylation of azoles with sodium sulfinates using Cu(OAc)(2)·H(2)O as oxidant has been discovered. The reaction proceeded well for a range of different substrates under oxidative conditions. A series of aryl-substituted azoles have been synthesized in moderate to good yields.

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Sigma-Aldrich
2-Aminophenol, 99%