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  • Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes.

Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes.

Chemical communications (Cambridge, England) (2010-09-22)
Xiaoyu Yan, Yiqing Zhou, Chanjuan Xi
RESUMO

Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.

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Sigma-Aldrich
Allyl bromide, reagent grade, 97%, contains ≤1000 ppm propylene oxide as stabilizer