L-proline catalyzed asymmetric transfer aldol reaction between diacetone alcohol and aldehydes.

L-proline catalyzed asymmetric transfer aldol reaction between diacetone alcohol and aldehydes.

Chemical communications (Cambridge, England) (2004-10-30)

S Chandrasekhar, Ch Narsihmulu, N Ramakrishna Reddy, S Shameem Sultana

RESUMO

We demonstrate for the first time, L-proline as a chiral catalyst for transfer aldol reaction between aldehydes and diacetone alcohol.

MATERIAIS

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Sigma-Aldrich

4-Hydroxy-4-methyl-2-pentanone, 99%