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Supelco

Boron trifluoride - 1-butanol solution

~10% in 1-butanol (∼1.3 M), for GC derivatization, LiChropur™

Sinônimo(s):

BF3 - Butanol solution

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About This Item

Número CAS:
7637-07-2
Número MDL:
MFCD00011316
Código UNSPSC:
12000000
ID de substância PubChem:
329769284
NACRES:
NA.05

grau

for GC derivatization

Nível de qualidade

100

forma

solution

qualidade

LiChropur™
for esterification of fatty acids for GC purposes

adequação da reação

reagent type: derivatization reagent
reaction type: Alkylations

concentração

~10% in 1-butanol (∼1.3 M)

técnica(s)

gas chromatography (GC): suitable

densidade

0.87 g/mL at 20 °C

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

FB(F)F

InChI

1S/BF3/c2-1(3)4

chave InChI

WTEOIRVLGSZEPR-UHFFFAOYSA-N

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Categorias relacionadas

Aplicação

Learn more in the Product Information
Boron trifluoride-1-butanol solution may be used as a derivatization agent in the separation and identification of water‐soluble low‐molecular‐weight carboxylic acids using capillary electrophoresis (CE) and gas chromatography coupled with mass spectrometry (GC-MS).
Reagent for the esterification of carboxylic acids for GC analysis

Informações legais

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Palavra indicadora

Danger

Classificações de perigo

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A - STOT SE 3

Órgãos-alvo

Central nervous system, Respiratory system

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

95.0 °F - closed cup

Ponto de fulgor (°C)

35 °C - closed cup

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
BCCG3924
BCCD9963
BCCB8315
BCBV9593
BCBP6227V

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Capillary electrophoresis determinative and GC-MS confirmatory method for water-soluble organic acids in airborne particulate matter and vehicle emission.
Dabek-Zlotorzynska E, et al.
Journal of Separation Science, 28(13), 1520-1528 (2005)
T Mizuno et al.
The Journal of chemical physics, 136(7), 074305-074305 (2012-03-01)
Recoil frame photoelectron angular distributions (RFPADs) of BF(3) molecules are presented over the energy region of the shape resonance in the F 1s continuum. Time-dependent density functional theory calculations are also given to understand the shape resonance dynamics. The RFPADs
The influence of the acidity of ionic liquids on catalysis.
Xinjiang Cui et al.
ChemSusChem, 3(9), 1043-1047 (2010-08-18)
Casey R Wade et al.
Chemical communications (Cambridge, England), 46(34), 6380-6381 (2010-08-07)
The presence of a proximal cationic group in zwitterionic aryltrifluoroborates such as o-(Ph(2)MeP)C(6)H(4)(BF(3)) stabilizes these compounds against hydrolysis.
Ramanathan Rajaganesh et al.
Carbohydrate research, 345(12), 1649-1657 (2010-06-29)
BF(3).Et(2)O-catalysed O-glycosylation of 1,2,3-tri-O-acetyl-4,6-O-butylidene- and ethylidene-beta-d-glucopyranose with different aliphatic and aromatic alcohols proceeds for the most part with complete retention of anomeric configuration. Antioxidant activity of O-glycosides shows significant inhibition (IC(50) approximately 77%). 1,3-Dipolar cycloaddition of terminal alkyne derivatives of
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