930059

S-Phenyl methanethioate

• Sinônimo(s): Phenyl thioCORMate, Phenyl thioformate
• Fórmula empírica (Notação de Hill): C₇H₆OS
• Número CAS: 27064-03-5
• Peso molecular: 138.19
• Número MDL: MFCD32756471
• Código UNSPSC: 12352101
• NACRES: NA.06

Propriedades

• forma: liquid
• Nível de qualidade: 100
• índice de refração: n/D 1.586
• densidade: 1.134 g/mL
• temperatura de armazenamento: −20°C
• cadeia de caracteres SMILES: [H]C(SC1=CC=CC=C1)=O

Descrição

Aplicação

S-phenyl methanethioate is an effective CO releasing molecule (CORM) developed by the lab of Sarah Tasker as part of a series of thioformate based CORMs called thioCORMates. p-NO₂ phenyl thioformate generates CO over the course of several minutes to allow for on-demand generation of CO for variety of reactions.

This and the other thioCORMates are cost effective CORMs that when activated with simple amines, can be used to generate a near quantitative amount of CO safely without the usage of gas cylinders. These are compatible with a variety of carbonylation reactions, as well as existing COware glassware and components.

ThioCORMate: Tunable and Cost-Effective Carbon Monoxide-Releasing Molecule

Learn more about CO releasing molecules from Prof. Skrydstrup

Informações de segurança

• Pictogramas: GHS07
• Palavra indicadora: Warning
• Frases de perigo: H315,H319,H335
• Declarações de precaução: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Classificações de perigo: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Órgãos-alvo: Respiratory system
• Código de classe de armazenamento: 10 - Combustible liquids
• Classe de risco de água (WGK): WGK 3
• Ponto de fulgor (°F): 221.0 °F
• Ponto de fulgor (°C): 105 °C