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Merck
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Key Documents

P7875

Sigma-Aldrich

Periodic acid

ReagentPlus®, ≥99.0%

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About This Item

Formule empirique (notation de Hill):
H5IO6
Numéro CAS:
Poids moléculaire :
227.94
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352106
ID de substance PubChem :
Nomenclature NACRES :
NA.21

Niveau de qualité

Gamme de produits

ReagentPlus®

Pureté

≥99.0%

Forme

powder or crystals

Pertinence de la réaction

reagent type: oxidant

Technique(s)

toxicology assay: suitable

Pf

122 °C (lit.)

Solubilité

water: 100 mg/mL, clear, colorless

Chaîne SMILES 

OI(O)(O)(O)(O)=O

InChI

1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)

Clé InChI

TWLXDPFBEPBAQB-UHFFFAOYSA-N

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Description générale

Periodic acid, an oxoacid of iodine, is commonly used as a strong oxidizing agent. This inorganic acid is soluble in most solvents including water and ether.

Application

Periodic acid can be used in the following reactions:      
  • Oxidation of alcohols to ketones and aldehydes.
  • Oxidation hydroxylamine derivatives.    
  • Oxidation of arenes to quinones.

It can also be used:     
  • As a stoichiometric oxidant with chromium (IV) acetate for the oxidation of tertiary C−H bonds to tertiary alcohols.     
  • In combination with chromium oxide to oxidize primary alcohols to carboxylic acids; alkylbenzenes to benzoic acids; and cyclic benzyl ethers to the corresponding lactones.      
  • In the selective oxidation of sulfides to sulfoxides using FeCl3 as a catalyst.

Informations légales

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1B - STOT RE 1 Oral

Organes cibles

Thyroid

Code de la classe de stockage

5.1A - Strongly oxidizing hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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