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Key Documents

159417

Sigma-Aldrich

Hydroxylamine hydrochloride

ReagentPlus®, 99%

Synonyme(s) :

Hydroxylammonium chloride

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About This Item

Formule linéaire :
NH2OH · HCl
Numéro CAS:
Poids moléculaire :
69.49
Numéro Beilstein :
3539763
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352300
ID de substance PubChem :
Nomenclature NACRES :
NA.21

Pression de vapeur

0.001 hPa ( 50 °C)

Niveau de qualité

Gamme de produits

ReagentPlus®

Pureté

99%

Forme

crystalline

Technique(s)

inhibition assay: suitable

pH

2.5-3.5 (20 °C, 50 g/L)

Pf

155-157 °C (dec.) (lit.)

Densité

1.67 g/mL at 25 °C (lit.)

Chaîne SMILES 

Cl.NO

InChI

1S/ClH.H3NO/c;1-2/h1H;2H,1H2

Clé InChI

WTDHULULXKLSOZ-UHFFFAOYSA-N

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Description générale

Hydroxylamine hydrochloride (Hydroxylammonium chloride) participates in the synthesis of 1,2,4-oxadiazoles, secondary amides and tertiary amides.
Hydroxylamine hydrochloride (NH2OH.HCl) is a hygroscopic salt widely used as a reactant in electrophilic substitution reactions, oxidation, and reduction reactions. It is also used in the synthesis of nitriles, pyrazoles, isoxazoles, nitrones, and pyridine.

Application

Hydroxylamine hydrochloride can be used as a reactant:
  • in the synthesis of primary amides from aldehydes in the presence of cesium carbonate (Cs2CO3) as a catalyst.
  • in the conversion of alicyclic /aliphatic carbonyl compounds and the aromatic aldehydes into corresponding oximes.
  • in the one-pot synthesis of nitriles from aldehydes in the presence of sodium sulfate (anhyd) and sodium bicarbonate catalysts.
  • It can also be used as a reducing agent in the preparation of single-layer reduced graphene oxide (RGO) sheets and films.

Actions biochimiques/physiologiques

Inhibiteur MAO; inhibe l′aggrégation des plaquettes

Informations légales

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Mention d'avertissement

Warning

Classification des risques

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Irrit. 2 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral

Organes cibles

spleen

Code de la classe de stockage

4.1A - Other explosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


Certificats d'analyse (COA)

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