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791989

Sigma-Aldrich

PDPP2T-TT-OD

Synonyme(s) :

Diketopyrrolopyrrole - thienothiophene copolymer, Diketopyrrolopyrrole p-type semiconductor, Xerox XSC4p

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About This Item

Formule linéaire :
(C60H90N2O2S4)n
Numéro CAS:
Code UNSPSC :
12352103
Nomenclature NACRES :
NA.23

Forme

solid

Poids mol.

average Mw 40,000-60,000 by GPC

Couleur

dark blue

Pf

>200 °C

λmax

820 nm (thin film)

Énergie orbitale

HOMO 5.2 eV 

Performance des dispositifs OFET

Bottom gate top contact device with silane modified SiO2 dielectric.Processing method spin coating; thermal annealing at 140 °C/ 10 min

  • Semiconductor Type:
  • Mobility: 0.60 cm2/V·s
  • On/Off Ratio: 10^6 - 10^7

PDI

2.5‑3.0

Description générale

PDPP2T-TT-OD is thiophene based conducting polymer with diketopyrrolo-pyrrole (DPP) as the electron deficient group and octyldodecyl acting as a pendant attachment. Its structure has a DPP-thiophene and a variable bithiophene (2T). It has a high charge carrying mobility that makes it useful in the development of organic electronics based devices.

Application

PDPP2T-TT-OD can be used as a π-conjugating polymer that can be used in the fabrication of a variety of devices such as organic thin film transistors (OTFTs), photovoltaic cells, polymeric solar cells and field effect transistors (FETs).
Xerox demonstrated device performance on a n-doped silicon wafer with 100 - 300 nm native SiO2 dielectric modified with an octadecyltrichlorosilane self-assembled
monolayer. An XSC4p film was deposited by spin-coating a 0.5 – 0.7 wt. % polymer solution at 1000 rpm for 60 sec. The film was dried in a vacuum oven for 10 min at 80
°C and then thermally annealed at 140 °C for 10 min. Gold source-drain electrodes were deposited by vacuum evaporation using a shadow mask (90 micrometer channels).
The electrical performance was characterized using a Keithley SCS-4200 system. The reported mobility is the average saturated mobility of four devicεs ± the standard
deviation.

Informations légales

Product of Xerox®. Xerox® is a registered trademark of Xerox Corporation.
Xerox is a registered trademark of Xerox Corporation

Pictogrammes

Exclamation mark

Mention d'avertissement

Warning

Mentions de danger

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Consulter la Bibliothèque de documents

Xinran Zhang et al.
Journal of the American Chemical Society, 133(38), 15073-15084 (2011-08-06)
We describe a series of highly soluble diketo pyrrolo-pyrrole (DPP)-bithiophene copolymers exhibiting field effect hole mobilities up to 0.74 cm(2) V(-1) s(-1), with a common synthetic motif of bulky 2-octyldodecyl side groups on the conjugated backbone. Spectroscopy, diffraction, and microscopy
Universal correlation between fibril width and quantum efficiency in diketopyrrolopyrrole-based polymer solar cells
Li W, et al.
Journal of the American Chemical Society, 135(50), 18942-18948 (2013)
Weiwei Li et al.
Advanced materials (Deerfield Beach, Fla.), 25(23), 3182-3186 (2013-03-07)
A high-molecular-weight conjugated polymer based on alternating electron-rich and electron-deficient fused ring systems provides efficient polymer solar cells when blended with C60 and C70 fullerene derivatives. The morphology of the new polymer/fullerene blend reduces bimolecular recombination and allows reaching high
Molecular packing of high-mobility diketo pyrrolo-pyrrole polymer semiconductors with branched alkyl side chains
Zhang X, et al.
Journal of the American Chemical Society, 133(38), 15073-15084 (2011)
Copolymers of diketopyrrolopyrrole and thienothiophene for photovoltaic cells
Bijleveld JC, et al.
Journal of Materials Chemistry, 21(25), 9224-9231 (2011)

Articles

The development of high-performance conjugated organic molecules and polymers has received widespread attention in industrial and academic research.

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