755745
2,2′-Azobis(2-methylpropionitrile)
recrystallized from methanol, 99%
Synonyme(s) :
α,α′-Azoisobutyronitrile, AIBN, Azobisisobutyronitrile, Free radical initiator
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About This Item
Formule linéaire :
(CH3)2C(CN)N=NC(CH3)2CN
Numéro CAS:
Poids moléculaire :
164.21
Numéro Beilstein :
1708400
Numéro CE :
Numéro MDL:
Code UNSPSC :
12162002
ID de substance PubChem :
Nomenclature NACRES :
NA.23
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Niveau de qualité
Pureté
99%
Forme
crystals
Pf
102-104 °C (dec.) (lit.)
103-107 °C
Température de stockage
−20°C
Chaîne SMILES
CC(C)(\N=N\C(C)(C)C#N)C#N
InChI
1S/C8H12N4/c1-7(2,5-9)11-12-8(3,4)6-10/h1-4H3/b12-11+
Clé InChI
OZAIFHULBGXAKX-VAWYXSNFSA-N
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Description générale
This AIBN was recrystallized and is ready for use as a polymerization initiator.
Application
- Porous Acid-Base Hybrid Polymers for Enhanced NH3 Uptake: This study discusses the use of 2,2′-Azobis(2-methylpropionitrile) in the synthesis of acid-base hybrid polymers, highlighting its role in enhancing ammonia uptake through cooperative hydrogen bonds (X Luo, Y Liu, et al., 2023).
- Extraction of Fluoroquinolones from Milk: The development of molecularly imprinted polymers using 2,2′-Azobis(2-methylpropionitrile) as an initiator for the extraction of antibiotics from milk showcases its application in food safety and pharmaceutical analysis (E Megias-Pérez, et al., 2023).
- Thermo-responsive Copolymer Visible Light Catalyst: Highlighting the use of 2,2′-Azobis(2-methylpropionitrile) in the synthesis of thermo-responsive copolymers, this study explores its applications in catalysis and material science, particularly in photoreactive polymers (S Wu, et al., 2024).
Mention d'avertissement
Danger
Mentions de danger
Conseils de prudence
Classification des risques
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Self-react. C
Risques supp
Code de la classe de stockage
4.1A - Other explosive hazardous materials
Classe de danger pour l'eau (WGK)
WGK 2
Point d'éclair (°F)
122.0 °F
Point d'éclair (°C)
50 °C
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Organic letters, 14(22), 5692-5695 (2012-10-31)
In the presence of a catalytic amount of radical initiator AIBN, primary amines are oxidatively coupled to imines and tertiary amines are cyanated to α-aminonitriles. These "metal-free" aerobic oxidative coupling reactions may find applications in a wide range of "green"
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Journal of endodontics, 37(2), 246-249 (2011-01-18)
We have developed new urethane acrylate-based root canal sealers using polycarbonate (PC) as polyol and 2,2-azobis(2-methyl)butyronitrile (AMBN) as a thermal initiator. The purpose of this study was to compare the properties among a group of seven sealers: (1) polybutyleneadipate (PBA)
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Macromolecular rapid communications, 32(1), 74-81 (2011-03-25)
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A novel class of nonionic amphipols (NAPols) designed to handle membrane proteins in aqueous solutions has been synthesized, and its solution properties have been examined. These were synthesized through free radical cotelomerization of glucose-based hydrophilic and amphiphilic monomers derived from
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