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Key Documents

Autres documents

743003

Sigma-Aldrich

2-Butanone peroxide

technical

Synonyme(s) :

Ethyl methyl ketone peroxide, Methyl ethyl ketone peroxide

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About This Item

Formule linéaire :
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
Numéro CAS:
1338-23-4
Poids moléculaire :
210.22
Numéro Beilstein :
1759757
Numéro MDL:
MFCD00042641
Code UNSPSC :
12352120
ID de substance PubChem :
329765606
Nomenclature NACRES :
NA.22

Qualité

technical

Forme

liquid

Contient

2,2,4-trimethyl-1,3-pentanediol-diisobutyrate as stabilizer

Pertinence de la réaction

reagent type: oxidant

Indice de réfraction

n20/D 1.432

Densité

1.053 g/mL at 20 °C (lit.)

Température de stockage

2-8°C

Chaîne SMILES 

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

Clé InChI

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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Application

Reactant for:
  • Studies of the adiabatic runaway reaction of Me Et Ketone peroxide
  • Quantitation of metal ions in archaeological glass via abrasive stripping square-wave voltammetry
  • Imaging of hydrogen peroxide and hydrogen peroxide-scavenging substances by photon emission
  • Synthesis of oligonucleotides via phosphoramidite method
  • Oxidation of nucleoside phosphites into phosphates
  • Comparing the relative effectiveness of human plasma glutathione peroxidase as a catalyst for reduction of hydroperoxidases

Analyte for direct electrochemical catalystis of immobilized Hb in an ethanol-water mixture

Pictogrammes

FlameCorrosionExclamation mark
GHS02,GHS05,GHS07

Mention d'avertissement

Danger

Mentions de danger

H226,H242,H302,H314

Classification des risques

Acute Tox. 4 Oral - Flam. Liq. 3 - Org. Perox. D - Skin Corr. 1B

Code de la classe de stockage

5.2 - Organic peroxides and self-reacting hazardous materials

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

132.8 °F - closed cup

Point d'éclair (°C)

56 °C - closed cup

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

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2-Butanone Pharmaceutical Secondary Standard; Certified Reference Material

Supelco

PHR1207

2-Butanone

F T Fraunfelder et al.
American journal of ophthalmology, 110(6), 635-640 (1990-12-15)
Methyl ethyl ketone peroxide is a commonly used catalyst in various industries. We studied 19 eyes with a single exposure to methyl ethyl ketone peroxide that developed clinical patterns of mild injury, moderate injury, severe injury, or delayed keratitis. Delayed
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
M Ando et al.
Chemico-biological interactions, 55(3), 317-326 (1985-11-01)
The effect of dietary vitamin E on in vivo and in vitro damage by methyl ethyl ketone peroxide (MEKP) to cytochrome P-450 and its associated enzymatic activity was studied. In vivo, MEKP damaged microsomal cytochrome P-450 and cytochrome P-450-mediated peroxidases
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The
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