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Key Documents

499811

Sigma-Aldrich

Lithium

granular, 99% trace metals basis

Synonyme(s) :

Lithium atom, Lithium element

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About This Item

Formule linéaire :
Li
Numéro CAS:
Poids moléculaire :
6.94
Numéro CE :
Numéro MDL:
Code UNSPSC :
12141803
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Pureté

99% trace metals basis

Forme

granular

Pertinence de la réaction

reagent type: reductant

Résistivité

9.446 μΩ-cm, 20°C

Point d'ébullition

1342 °C (lit.)

Pf

180 °C (lit.)

Densité

0.534 g/mL at 25 °C (lit.)

Chaîne SMILES 

[Li]

InChI

1S/Li

Clé InChI

WHXSMMKQMYFTQS-UHFFFAOYSA-N

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Description générale

Granular lithium is a form of lithium metal that has been ground into small granules. Lithium is a soft, silver-white metal that is highly reactive and flammable. Lithium has a low density of 0.534 g/cm3, which makes it one of the lightest metals. Like the other alkali metals, lithium has a low melting point (180 °C) and is a good conductor of electricity and heat. Granular lithium is highly reactive and behaves as a strong reducing agent. It must be handled with caution due to its potential to ignite or explode. Lithium reacts readily with water and oxygen to form lithium hydroxide and lithium oxide, respectively, and even reacts with nitrogen gas at room temperature, forming lithium nitride. Typically, lithium is stored in an argon glovebox and airtight containers to prevent exposure to moisture, air, and nitrogen. To make granular lithium, the metal is first extracted from ores such as spodumene or lepidolite using a process called lithium carbonate conversion. After the lithium has been purified to a high degree of purity, it is milled into granules by rotating blades.
Lithium is a low-density alkali metal that is widely used as an anode material in rechargeable and non-rechargeable batteries. It is also used to alloy with aluminum and magnesium to make them stronger and lighter.

Application

Lithium can be used as:
  • A precursor to synthesize Li-based alloys such as LiAl and LiSi alloys, which are applicable as anode materials in the field of energy conversion and storage.
  • A reducing agent in the reduction of zirconium oxide compounds in molten LiCl salt.
  • As starting material to synthesize a reducing agent(1,4-bis(trimethylgermyl)-1.4-dihydropyrazine), for the fabrication of nickel metal films.

Pictogrammes

FlameCorrosion

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Skin Corr. 1B - Water-react 1

Risques supp

Code de la classe de stockage

4.3 - Hazardous materials which set free flammable gases upon contact with water

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Certificats d'analyse (COA)

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Les clients ont également consulté

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A low-temperature thermal ALD process for nickel utilizing dichlorobis(triethylphosphine)nickel(ii) and 1{,}4-bis(trimethylgermyl)-1{,}4-dihydropyrazine"
Anton Vihervaara,
Dalton Transactions, 51, 10898-10908 (2022)
U Eismann et al.
Optics express, 21(7), 9091-9102 (2013-04-11)
We present an all-solid-state laser source emitting up to 2.1 W of single-frequency light at 671 nm developed for laser cooling of lithium atoms. It is based on a diode-pumped, neodymium-doped orthovanadate (Nd:YVO(4)) ring laser operating at 1342 nm. Optimization
M Sathiya et al.
Nature materials, 12(9), 827-835 (2013-07-16)
Li-ion batteries have contributed to the commercial success of portable electronics and may soon dominate the electric transportation market provided that major scientific advances including new materials and concepts are developed. Classical positive electrodes for Li-ion technology operate mainly through
Enikö Zörgö et al.
PLoS genetics, 9(3), e1003388-e1003388 (2013-04-05)
The number of chromosome sets contained within the nucleus of eukaryotic organisms is a fundamental yet evolutionarily poorly characterized genetic variable of life. Here, we mapped the impact of ploidy on the mitotic fitness of baker's yeast and its never
Jian Jiang et al.
Nanoscale, 5(17), 8105-8113 (2013-07-26)
Controlled integration of multiple semiconducting oxides into each single unit of ordered nanotube arrays is highly desired in scientific research for the realization of more attractive applications. We herein report a diffusion-controlled solid-solid route to evolve simplex Co(CO3)0.5(OH)0.11H2O@TiO2 core-shell nanowire

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