498491

4-Ethoxy-4-oxobutylzinc bromide solution

0.5 M in THF

• Synonym(s): (4-Ethoxy-4-oxobutyl)zinc(II) bromide, Bromo[4-ethoxy-4-(oxo-κO)butyl-κC]zinc
• Linear Formula: C₂H₅O₂C(CH₂)₃ZnBr
• CAS Number: 131379-39-0
• Molecular Weight: 260.44
• MDL number: MFCD00671977
• UNSPSC Code: 12352103
• PubChem Substance ID: 24873202
• NACRES: NA.22

Properties

• Quality Level: 100
• concentration: 0.5 M in THF
• density: 0.976 g/mL at 25 °C
• storage temp.: 2-8°C
• SMILES string: CCOC(=O)CCC[Zn]Br
• InChI: 1S/C6H11O2.BrH.Zn/c1-3-5-6(7)8-4-2;;/h1,3-5H2,2H3;1H;/q;;+1/p-1
• InChI key: QRIVZBPOANGBFR-UHFFFAOYSA-M

Description

Application

4-Ethoxy-4-oxobutylzinc bromide can be used:

• As an intermediate in one of the key synthetic steps for the preparation of acrylic acid derivatives as EP3 receptor antagonists.
• As an intermediate in the final step of the total synthesis of a natural product mucosin.
• As a substrate in the synthesis of multi-substituted haloalkenes by reacting with 1-haloalkenes via Negishi cross-coupling reaction.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Safety Information

• Pictograms: GHS07,GHS08
• Signal Word: Warning
• Hazard Statements: H319 - H335 - H351
• Precautionary Statements: P261 - P281 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 3
• Flash Point(F): -6.2 °F - (THF)
• Flash Point(C): -21.2 °C - (THF)