77645

Bupirimate-(ethyl-d₅)

PESTANAL^®, analytical standard

• Synonym(s): N,N-Dimethylsulfamic acid 5-butyl-2-(ethyl-d₅-amino)-6-methyl-4-pyrimidinyl ester, Bupirimate-d₅
• Empirical Formula (Hill Notation): C₁₃D₅H₁₉N₄O₃S
• Molecular Weight: 321.45
• UNSPSC Code: 12352200
• PubChem Substance ID: 329767838
• NACRES: NA.24

Properties

• grade: analytical standard
• Quality Level: 100
• product line: PESTANAL^®
• Assay: ≥98.0% (HPLC)
• shelf life: limited shelf life, expiry date on the label
• application(s): agriculture
• format: neat
• storage temp.: 2-8°C
• SMILES string: CC1=NC(NC([2H])([2H])C([2H])([2H])[2H])=NC(OS(N(C)C)(=O)=O)=C1CCCC

Description

General description

Bupirimate-(ethyl-d₅) is an isotope-labeled analog of the local systemic fungicide bupirimate, wherein all the ethyl protons are replaced by deuterium.

Application

Isotope-labeled compounds are increasingly used in isotope dilution mass spectrometry (IDMS) for the quantitative analysis of pesticides. The main advantage of using the IDMS technique is because isotope-labeled compounds have nearly the same physical properties as their non-labeled counterpart analog, and thus show identical behavior during the workup and sample preparation process. This helps in overcoming the problems of matrix effects generally encountered in the usual LC-MS/GC-MS analysis potentially resulting in biased results. By spiking the sample before workup with its isotope labeled analog, the loss of analyte that leads to matrix effects can be determined and compensated.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS06
• Signal Word: Danger
• Hazard Statements: H311
• Precautionary Statements: P280 - P302 + P352 + P312
• Hazard Classifications: Acute Tox. 3 Dermal
• Storage Class Code: 6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable