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900432

Sigma-Aldrich

Tetra-n-butylammonium decatungstate

Synonym(s):

1-Butanaminium, N,N,N-tributyl-, eicosa-μ-oxodi-μ5-oxodecaoxodecatungstate (4:1), 1-Butanaminium, N,N,N-tributyl-, salt with tungstic acid (4:1), TBADT, Tetrakis(N,N,N-tributyl-1-butanaminium) tungstate, Tetrakis(tetrabutylammonium) decatungstate

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About This Item

Empirical Formula (Hill Notation):
C64H144N4O32W10
CAS Number:
68109-03-5
Molecular Weight:
3320.24
UNSPSC Code:
12352103
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

core: tungsten
reaction type: C-H Activation
reaction type: Photocatalysis
reagent type: catalyst

Related Categories

Application

When used in conjunction with cobaloxime pyridine chloride (341630), this complex can effect the catalytic, room-temperature dehydrogenation of unactivated alkanes under solar irradiation with hydrogen as the sole byproduct.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis

C(sp3)–H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

related product

Product No.
Description
Pricing

919349

NaDT

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Articles

Dehydrogenation through Cooperative Base Metal Catalysis

The Sorensen group has reported a dual-catalytic system capable of dehydrogenating alkanes & alcohols at low temperatures with hydrogen gas as the sole byproduct

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