744034

Triphenylphosphine-3,3′,3′′-trisulfonic acid trisodium salt

≥95.0%

• Synonym(s): 3,3′,3″-Phosphinidynetris(benzenesulfonic acid) trisodium salt, Tris(3-sulfophenyl)phosphine trisodium salt
• Linear Formula: P(C₆H₄SO₃Na)₃
• CAS Number: 63995-70-0
• Molecular Weight: 568.42
• Beilstein: 3584807
• EC Number: 264-596-6
• MDL number: MFCD00145472
• UNSPSC Code: 12352107
• PubChem Substance ID: 329765671
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: ≥95.0%
• form: powder
• composition: sulfur, 16.07-17.76%
• impurities: ≤10% water
• SMILES string: [Na+].[Na+].[Na+].[O-]S(=O)(=O)c1cccc(c1)P(c2cccc(c2)S([O-])(=O)=O)c3cccc(c3)S([O-])(=O)=O
• InChI: 1S/C18H15O9PS3.3Na/c19-29(20,21)16-7-1-4-13(10-16)28(14-5-2-8-17(11-14)30(22,23)24)15-6-3-9-18(12-15)31(25,26)27;;;/h1-12H,(H,19,20,21)(H,22,23,24)(H,25,26,27);;;/q;3*+1/p-3
• InChI key: MYAJTCUQMQREFZ-UHFFFAOYSA-K

Description

Application

Triphenylphosphine-3,3′,3′′-trisulfonic acid trisodium salt (TPPTS) can be used as a capping agent in the synthesis of TPPTS stabilized palladium nanoparticles (PdNPs) using K₂PdCl₄ as the palladium source and HCOONa as the reductant. The TPPTS stabilized PdNPs are applicable as an efficient catalyst in the aqueous phase Suzuki-Miyaura coupling reaction at room temperature. TPPTS is also used as a ligand in the metal-catalyzed hydroformylation of functionalized olefins and direct arylation polymerization reactions.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 1
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable