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Key Documents

711268

Sigma-Aldrich

N-tert-Butyl-O-[1-[4-(chloromethyl)phenyl]ethyl]-N-(2-methyl-1-phenylpropyl)hydroxylamine

Synonym(s):

Alkoxyamine NMP initiator

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About This Item

Empirical Formula (Hill Notation):
C23H32ClNO
CAS Number:
Molecular Weight:
373.96
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

solid

mp

43-47 °C

storage temp.

−20°C

SMILES string

CC(C)C(N(OC(C)c1ccc(CCl)cc1)C(C)(C)C)c2ccccc2

InChI

1S/C23H32ClNO/c1-17(2)22(21-10-8-7-9-11-21)25(23(4,5)6)26-18(3)20-14-12-19(16-24)13-15-20/h7-15,17-18,22H,16H2,1-6H3

InChI key

WZYBDTCNEIULNZ-UHFFFAOYSA-N

Related Categories

General description

For a synthetic protocol using NMP initiators, contributed by Prof. Karen Wooley, please visit our technology spotlight.

Pictograms

Flame over circleCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Ox. Sol. 3 - Skin Corr. 1B

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

230.0 °F - closed cup

Flash Point(C)

> 110 °C - closed cup


Certificates of Analysis (COA)

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Articles

A detailed article on block copolymer synthesis using a nitroxide-mediated radical polymerization (NMP) approach.

Block copolymer synthesis using a commercially available nitroxide-mediated radical polymerization (NMP) initiator

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

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Protocols

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

An article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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