696668
Nickel(II) chloride ethylene glycol dimethyl ether complex
98%
Synonym(s):
Dichloro(dimethoxyethane)nickel, NiCl2 glyme
About This Item
Recommended Products
Assay
98%
form
powder
reaction suitability
core: nickel
reagent type: catalyst
mp
>300 °C
SMILES string
Cl[Ni]Cl.COCCOC
InChI
1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2
InChI key
OCMNCWNTDDVHFK-UHFFFAOYSA-L
Application
- As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.
- As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.
- For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.
- As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Water-react 2
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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Nickel transition metal and its complexes can be used as a catalyst in many synthetic transformations, like oxidative addition, C-H activation, reductive elimination, oxidative cyclization, oligomerization, and in cross-coupling reactions.
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