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658383

Sigma-Aldrich

Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III)

Synonym(s):

[(ppy)2IrCl]2

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About This Item

Empirical Formula (Hill Notation):
C44H32Cl2Ir2N4
CAS Number:
Molecular Weight:
1072.09
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

form

solid

Quality Level

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

photocatalyst activation

465 nm

SMILES string

Cl[Ir](c1ccccc1-c2ccccn2)c3ccccc3-c4ccccn4.Cl[Ir](c5ccccc5-c6ccccn6)c7ccccc7-c8ccccn8

InChI

1S/4C11H9N.2ClH.2Ir/c4*1-2-6-10(7-3-1)11-8-4-5-9-12-11;;;;/h4*1-9H;2*1H;;/q;;;;;;2*+1/p-2

InChI key

NARZJSRZFGZBIZ-UHFFFAOYSA-L

Application

Precursor for several OLED Iridium compounds. Has some use as a catalyst and in OLEDs.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Journal of the American Chemical Society, 106, 6647-6647 (1984)

Articles

Since their discovery, organic light emitting devices (OLEDs) have evolved from a scientific curiosity into a technology with applications in flat panel displays and the potential to revolutionize the lighting market. During their relatively short history, the technology has rapidly advanced, and device efficiencies have increased more than 20-fold, approaching the theoretical limit for internal quantum efficiencies.

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